Recently I am researching about HOMOGENEOUS SYSTEM; DIFFERENT SOLVENTS; H-2 EVOLUTION; COBALT; COMPLEXES; MECHANISM; COBALOXIMES; PHOTOSENSITIZERS; ABSORPTION; DISCOVERY, Saw an article supported by the National Science Foundation (NSF)National Science Foundation (NSF) [CHE 1764353]; Carnegie Mellon University’s Kavcic-Moura Fund and Manufacturing Futures Initiative; Steinbrenner Institute Graduate Fellowship; ARCS Foundation Pittsburgh Chapter; Fulbright Future Scholarship. Category: pyridine-derivatives. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Motz, RN; Lopato, EM; Connell, TU; Bernhard, S. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone
Noble-metal photosensitizers and water reduction co-catalysts (WRCs) still present the highest activity in homogeneous photocatalytic hydrogen production. The search for earth-abundant alternatives is usually limited by the time required to screen new catalyst combinations; however, here, we utilize newly designed and developed high-throughput photoreactors for the parallel synthesis of novel WRCs and colorimetric screening of hydrogen evolution. This unique approach allowed rapid optimization of photocatalytic water reduction using the organic photosensitizer Eosin Y and the archetypal cobaloxime WRC [Co(GL1)(2)pyCl], where GL1 is dimethylglyoxime and py is pyridine. Subsequent combinatorial synthesis generated 646 unique cobalt complexes of the type [Co(LL)(2)pyCl], where LL is a bidentate ligand, that identified promising new WRC candidates for hydrogen production. Density functional theory (DFT) calculations performed on such cobaloxime derivative complexes demonstrated that reactivity depends on hydride affinity. Alkyl-substituted glyoximes were necessary for hydrogen production and showed increased activity when paired with ligands containing strong hydrogen-bond donors.
About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Motz, RN; Lopato, EM; Connell, TU; Bernhard, S or concate me.. Category: pyridine-derivatives
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem