An article Selective oxidation of alcohols by porphyrin-based porous polymer-supported manganese heterogeneous catalysts WOS:000500737400001 published article about COVALENT ORGANIC FRAMEWORKS; RACEMIC SECONDARY ALCOHOLS; KINETIC RESOLUTION; METAL-CATALYSTS; CO2; CARBON; HYDROGENATION; CRYSTALLINE; MECHANISM; CU in [Chen, Jian; Zhang, Yan] Huanggang Normal Univ, Sch Chem & Chem Engn, Hubei Key Lab Proc & Applicat Catalyt Mat, 146,Xingang 2 Rd, Huanggang City 438000, Hubei, Peoples R China; [Chen, Jian; Zhu, Dajian; Li, Tao] Huazhong Univ Sci & Technol, Hubei Key Lab Mat Chem & Serv Failure, 1073 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China; [Chen, Jian; Zhu, Dajian; Li, Tao] Huazhong Univ Sci & Technol, Minist Educ, Key Lab Mat Chem Energy Convers & Storage, 1073 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China; [Chen, Jian; Zhu, Dajian; Li, Tao] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, 1073 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China in 2020.0, Cited 53.0. The Name is 3-Pyridinecarboxaldehyde. Through research, I have a further understanding and discovery of 500-22-1. Safety of 3-Pyridinecarboxaldehyde
A series of porphyrin-based porous polymers to support Mn heterogeneous catalysts (Mn/TFP-DPM, Mn/TFP-DPM-2, Mn/TFP-DPM-3, and Mn/TFP-DPM-4) in the selective oxidation of alcohols were designed. TFP-DPM and TFP-DPM-2 demonstrated micro/nanoscale spherical morphology, whereas TFP-DPM-3 and TFP-DPM-4 exhibited nanosheets structure. According to surface area and porosity analysis results, the specific surface areas of these catalysts were less than 300 m(2) g(-1). Thermogravimetric analysis indicated that the synthesized catalysts maintain their stability even at 300 degrees C. Catalysts Mn/TFP-DPM and Mn/TFP-DPM-3, which had the smallest and largest specific surface area among the four catalysts, respectively, were used to perform selective oxidation reaction of alcohols, with experimental results indicating that both have excellent catalytic performance. As these catalysts possess good catalytic performance despite their low specific surface area, we suggest that porphyrin-based porous polymer-supported Mn heterogeneous catalysts are promising materials for selective oxidation of alcohols.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem