Computed Properties of C12H9NO. Sutradhar, D; Chowdhury, H; Banerjee, S; Saha, NC; Ghosh, BK in [Sutradhar, Dipu; Ghosh, Barindra Kumar] Univ Burdwan, Dept Chem, Burdwan 713104, W Bengal, India; [Chowdhury, Habibar] Kabi Nazrul Coll, Dept Chem, Birbhum 731219, W Bengal, India; [Banerjee, Somnath] HBNI, Natl Inst Sci Educ & Res, Sch Chem Sci, Khorda 52050, Odisha, India; [Saha, Nimai Chandra] Univ Burdwan, Dept Zool, Vice Chancellors Res Grp, Burdwan 713104, W Bengal, India published Syntheses, crystal structures and luminescence behaviors of four neutral penta-/hexacoordinate cadmium(II) compounds containing a tridentate Schiff base: Variation in coordination numbers, nuclearities and dimensionalities by changing halides/pseudohalides in 2019.0, Cited 120.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.
Two neutral pentacoordinate mononuclear cadmium(II) complexes of the type [Cd(L)X-2] [L = N-(pyridin-2′-yl)benzylidene)-2-(piperidin-1-yl)ethane-1,2-diamine; X = Cl, (1) and X = Br, (2)], one neutral hexacoordinate dinuclear compound [Cd(L)(mu-NCS)NCS](2) (3) and one neutral hexacoordinate coordination polymer [Cd(L)(mu-N-3)N-3](n) (4) have been prepared and characterized using microanalytical, spectroscopic, thermal and X-ray crystallographic results. Structural analyses show that each cadmium(II) center in the isostructural compounds 1 and 2 adopts a distorted square pyramidal geometry with a CdN3X2 [X = Cl in 1 and X = Br in 2] chromophore through coordination of three N atoms of L and two terminal halides. In 3 and 4, each metal(II) center affords a distorted octahedral geometry with MN5S (in 3) and MN6 (in 4) chromophores. Each metal(II) center in dinuclear compound 3 is attached to three N-atoms of L, one N-atom of terminal thiocyanate, and one N-atom and one S-atom of two mu(1,3)-bridging thiocyanate units, whereas three N-atoms of L and three N-atoms of one terminal and two mu(1,3)-bridging azide units are bound to each metal(II) center in the coordination polymer 4. Each metal (II) center in 4 is connected to two other metal(II) centers through two different mu(1,3)-azide bridges affording a zigzag one-dimensional (1D) chain. In the crystalline state, mononuclear units in both 1 and 2 are stabilized through intermolecular C-H center dot center dot center dot X (X = Cl in 1 and X = Br in 2) hydrogen bonds promoting to 2D sheet structures. The dinuclear units in 3 pack through cooperative intermolecular C-H center dot center dot center dot S and C-H center dot center dot center dot N hydrogen bonds giving rise to a 3D network structure. 1D chains in 4 are stabilized through cooperative intermolecular C-H center dot center dot center dot N hydrogen bonds promoting to a 2D sheet structure. These 2D sheets, in turn, self-assemble through weak noncovalent pi center dot center dot center dot pi interactions to afford a 3D network structure. The thermally stable compounds (1-4) exhibit intraligand (1)(pi-pi*) fluorescence in DMF solutions at room temperature with lifetimes in range 0.83-2.94 ns.
Computed Properties of C12H9NO. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Sutradhar, D; Chowdhury, H; Banerjee, S; Saha, NC; Ghosh, BK or concate me.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem