So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Bollenbach, Maud; Lecroq, William; Wagner, Patrick; Fessard, Thomas; Schmitt, Martine; Salome, Christophe researched the compound: 5-(di-tert-Butylphosphino)-1′,3′,5′-triphenyl-1’H-1,4′-bipyrazole( cas:894086-00-1 ).Product Details of 894086-00-1.They published the article 《On water N-arylation of oxetanylamines for the preparation of N-aryl-oxetanylamines; potentially useful aryl-amide isosteres》 about this compound( cas:894086-00-1 ) in Chemical Communications (Cambridge, United Kingdom). Keywords: aryl oxetanylamine preparation water surfactant tocopherol methoxypolyethylene glycol succinate; oxetanylamine aryl halide palladium cross coupling. We’ll tell you more about this compound (cas:894086-00-1).
A Pd cross-coupling approach for the synthesis of N-aryl-oxetanylamines I (R = 2-Me, 3-F, 3-MeO etc.) has been developed. This method provides new building blocks potentially useful in medicinal chem. as amide bioisosteres. The reactions are conducted in water employing the renewable feedstock surfactant TPGS-750-M ( DL-α-Tocopherol methoxypolyethylene glycol succinate).
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