Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 3375-31-3, is researched, SMILESS is CC([O-])=O.CC([O-])=O.[Pd+2], Molecular C4H6O4PdJournal, Chinese Journal of Chemistry called Synthesis of Axially Chiral Anilides Enabled by a Palladium/ Ming-Phos-Catalyzed Desymmetric Sonogashira Reaction, Author is Yang, Bin; Yang, Junfeng; Zhang, Junliang, the main research direction is axially chiral anilide preparation enantioselective; palladium ming phos catalyst desym sonogashira reaction.Name: Palladium(II) acetate.
Atropisomeric anilides are one of important C-N axially chiral compounds Compared with the N-terminal functionalization to prepare such compounds, C-terminal functionalization strategies have been rarely reported. Authors describe herein an efficient synthesis of axially chiral anilides enabled by Pd-catalyzed desym. Sonogashira cross-coupling reactions with the use of a newly identified Ming-Phos. Moderate to high yields with high enantioselectivities (up to 98% ee) were obtained.
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