Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 3375-31-3, is researched, Molecular C4H6O4Pd, about Water-mediated hydrogen spillover accelerates hydrogenative ring-rearrangement of furfurals to cyclic compounds, the main research direction is water hydrogen spillover hydrogenative ring rearrangement furfural cyclic.COA of Formula: C4H6O4Pd.
Upgrading bioderived furfurals (furfural, 5-hydroxymethylfurfural) to cyclopentanones (cyclopentanone, 3-hydroxymethylcyclopentanone) and cyclopentanols (cyclopentanol, 3-hydroxymethylcyclopentanol) is a representative bifunctional catalytic process in biomass conversion. Here, a class of Pd/NiMoO4 catalysts (Pd/NiMoO4-Cl, Pd/NiMoO4-AC) with low Pd loading (1.0 wt%) and different Pd dispersion are synthesized. The hydrogenation active sites and acidic sites of catalysts were adjusted by a water-mediated hydrogen spillover process. 56.3-85.3% yields of cyclopentanones and 65.4-85.2% yields of cyclopentanols were obtained by hydrogenative ring-rearrangement route of furfurals over Pd/NiMoO4-Cl and Pd/NiMoO4-AC, resp. Over-hydrogenated byproducts (tetrahydrofurfuryl alc., 2,5-bis(hydroxymethyl)tetrahydrofuran) with a yield above 54% were generated by a full hydrogenation route over Pd/C. The difference in catalytic performance is results from alteration of the adsorption configurations of reactants and the transformation of Lewis acid sites to Bronsted acid sites by hydrogen spillover. This work presents an effective strategy for governing reaction routes and enhancing bifunctional catalysis with a hydrogen spillover mechanism.
I hope my short article helps more people learn about this compound(Palladium(II) acetate)COA of Formula: C4H6O4Pd. Apart from the compound(3375-31-3), you can read my other articles to know other related compounds.