The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Palladium(II) acetate(SMILESS: CC([O-])=O.CC([O-])=O.[Pd+2],cas:3375-31-3) is researched.Name: 5,5′-Dimethyl-2,2′-bipyridine. The article 《A palladium-catalyzed sequential Heck coupling/C-C bond activation approach to oxindoles with all-carbon-quaternary centers》 in relation to this compound, is published in Organic & Biomolecular Chemistry. Let’s take a look at the latest research on this compound (cas:3375-31-3).
A palladium-catalyzed sequential Heck coupling/C-C bond activation of aryl halide-tethered alkenes with benzocyclobutenols affording a series of oxindole-derived compounds I [R = Me, cyclohexyl, Bn, etc.; R1 = H, Me; R2 = H, OMe, F, etc.; R3 = Me, Ph; R4 = Me, Et, Bn, etc.; R5 = H, OMe, OBn; R6 = H, OMe; R7 = H, Me, OMe; R8 = H, OMe] in good to excellent yields, as well as the preliminary enantioselectivity results was reported.
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