Reference of Picolinoyl chloride hydrochloride. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Picolinoyl chloride hydrochloride, is researched, Molecular C6H5Cl2NO, CAS is 39901-94-5, about An NADH-Inspired Redox Mediator Strategy to Promote Second-Sphere Electron and Proton Transfer for Cooperative Electrochemical CO2 Reduction Catalyzed by Iron Porphyrin. Author is Smith, Peter T.; Weng, Sophia; Chang, Christopher J..
The authors present a bioinspired strategy for enhancing electrochem. CO2 reduction catalysis by cooperative use of base-metal mol. catalysts with intermol. 2nd-sphere redox mediators that facilitate both electron and proton transfer. Functional synthetic mimics of the biol. redox cofactor NADH, which are electrochem. stable and are capable of mediating both electron and proton transfer, can enhance the activity of an Fe porphyrin catalyst for electrochem. reduction of CO2 to CO, achieving a 13-fold rate improvement without altering the intrinsic high selectivity of this catalyst platform for CO2 vs. proton reduction Evaluation of a systematic series of NADH analogs and redox-inactive control additives with varying proton and electron reservoir properties reveals that both electron and proton transfer contribute to the observed catalytic enhancements. Second-sphere dual control of electron and proton inventories is a viable design strategy for developing more effective electrocatalysts for CO2 reduction, providing a starting point for broader applications of this approach to other multielectron, multiproton transformations. The authors present a bioinspired strategy for enhancing electrochemcial CO2 reduction catalysis using a family of NADH mimics as dual electron/proton mediators. Combined with an Fe porphyrin cocatalyst, these intermol. 2nd-sphere additives can improve CO2 reduction to CO while maintaining high product selectivity with up to a 13-fold rate enhancement in activity.
In some applications, this compound(39901-94-5)Reference of Picolinoyl chloride hydrochloride is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.