So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Hierlmeier, Gabriele; Wolf, Robert researched the compound: Palladium(II) acetate( cas:3375-31-3 ).Electric Literature of C4H6O4Pd.They published the article 《Bulking up CpBIG: a penta-terphenyl cyclopentadienyl ligand》 about this compound( cas:3375-31-3 ) in ChemRxiv. Keywords: potassium pentaterphenylcyclopentadienyl sandwich complex preparation crystal structure; crystal structure lithium potassium pentaterphenylcyclopentadienyl sandwich complex; mol structure lithium potassium pentaterphenylcyclopentadienyl sandwich complex; lithium pentaterphenylcyclopentadienyl sandwich complex preparation crystal structure; sodium pentaterphenylcyclopentadienyl sandwich complex preparation; rubidium pentaterphenylcyclopentadienyl sandwich complex preparation; cesium pentaterphenylcyclopentadienyl sandwich complex preparation. We’ll tell you more about this compound (cas:3375-31-3).
The modification of cyclopentadienyl ligands with carefully selected substituents is a widely used strategy to tune their steric and electronic properties. The authors describe the synthesis of an extremely bulky penta-terphenyl cyclopentadienyl ligand (CpT5) by arylation of cyclopentadiene. Deprotonation reactions with various Group 1 metals and bases afforded a complete series of alkali metal salts MCpT5 with M = Li to Cs. The compounds were isolated as solvate-free salts, which were characterized by multinuclear NMR spectroscopy, UV-visible spectroscopy and elemental anal. Single-crystal x-ray diffraction studies on LiCpT5, NaCpT5 (crystallized as a solvate with one THF mol. per formula unit) and KCpT5 revealed the formation of metallocene-like sandwich structures in the solid state.
《Bulking up CpBIG: a penta-terphenyl cyclopentadienyl ligand》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Palladium(II) acetate)Electric Literature of C4H6O4Pd.