The important role of 2-(Pyridin-3-yl)benzoic acid

The synthetic route of 134363-45-4 has been constantly updated, and we look forward to future research findings.

Adding a certain compound to certain chemical reactions, such as: 134363-45-4, 2-(Pyridin-3-yl)benzoic acid, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound, Computed Properties of C12H9NO2, blongs to pyridine-derivatives compound. Computed Properties of C12H9NO2

A mixture of [2-[4-(4-amino-2-fluoro-phenyl)-piperazin-1 -yl]-lambda/-ethyl-2- phenyl-acetamide (320 mg, 0.90 mmol), 2-(3′-pyridyl) benzoic acid (200 mg, 0.99 mmol) and HATU (375 mg, 0.99 mmol) in DMF (10 ml_) was treated with DIPEA (170 mul_, 0.99 mmol) and let stir at room temperature for 6 h. The reaction mixture was quenched with H2O and extracted with EtOAc. The organic layer was separated and washed (sat’d NaHCO3, brine), dried (Na2SO4), filtered and concentrated to yield a semi solid, which was purified by PTLC (5% 2M NH3/MeOH in CH2CI2) to yield the title compound as a brown foam.MS (ESI): mass calcd. for C32H32FN5O;?, 537.64; m/z found, 538.5 [M+H]+. 1H NMR (CDCI3): 8.74-8.73 (m, 1 H), 8.62-8.60 (m, 1 H), 7.80-7.76 (m, 2H), 7.60-7.57 (m, 1 H), 7.54-7.50 (m, 1 H), 7.46-7.43 (m, 1 H), 7.33-7.29 (m, 6H), 7.18-7.15 (m, 1 H), 7.09-7.00 (m, 2H), 6.91 (s, 1 H), 6.84-6.77 (m, 1 H), 3.87 (s, 1 H), 3.35-3.32 (m, 2H), 3.05-3.04 (m, 4H), 2.61 -2.58 (m, 4H), 1.16 (t, J = 7.2, 3H)

The synthetic route of 134363-45-4 has been constantly updated, and we look forward to future research findings.

Reference:
Patent; JANSSEN PHARMACEUTICA, N.V.; WO2009/6185; (2009); A1;,
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem