Pyridine is colorless, but older or impure samples can appear yellow. 5315-25-3, formula is C6H6BrN, Name is 2-Bromo-6-methylpyridine. The pyridine ring occurs in many important compounds, including agrochemicals, pharmaceuticals, and vitamins. Historically, pyridine was produced from coal tar. Recommanded Product: 2-Bromo-6-methylpyridine.
Jain, Nimisha;Mary, Angelina;Manjunath, Vishesh;Sakla, Rahul;Devan, Rupesh S.;Jose, D. Amilan;Naziruddin, Abbas Raja research published 《 Ruthenium complexes bearing N-heterocyclic carbene based CNC and CNĈH2C’ pincer ligands: Photophysics, electrochemistry, and solar energy conversion》, the research content is summarized as follows. Ruthenium terpyridine-supported diimidazolylpyridine NHC complexes were prepared and examined for redox and photophys. properties. A combination of N-heterocyclic carbene (NHC) based C-N-C, or C-N-CH2C’ pincer ligands and carboxy-Ph terpyridine donors is used to prepare ruthenium complexes. The unsym. coordination of C-N-CH2C’ pincer ligand via the CN donor atoms gave a rigid five-membered ring, and binding through N-CH2C donor side rendered a six-membered chelate ring in [Ru(C-N-CH2C’)(4′-tpy-4-HO2CC6H4)](PF6)2. The latter binding gives the ruthenium center a near-ideal octahedral configuration with a more potent ligand field that could destabilize the thermally accessible-d-d states. The ambient condition excited-state lifetimes became consequently more prolonged than in the small-bite angle [Ru(C-N-C)(4′-tpy-4-HO2CC6H4)](PF6)2 congener. Enhancement of lifetimes could be essential for better electron injection into the TiO2 conduction band. Photophys. attributes of these complexes are studied to evaluate their potential use in dye-sensitized solar cells (DSSCs). The electrochem. and computational study also suggests a favorable regeneration of [Ru(C-N-CH2C’)(4′-tpy-4-HO2CC6H4)](PF6)2 bearing I–3/I–electrolyte in a DSSC set-up. We herein report the syntheses, photo-functional attributes, redox behavior, and the preliminary device characteristics. Computed geometries of complexes in different electronic states and the bonding attributes of NHC ligands in different pincer-motifs of C-N-C vs. C-N-CH2C’ are also reported.
5315-25-3, 2-Bromo-6-methylpyridine (2BMPy) is a bromopyridine derivative. It is formed when 2-chloro-6-methylpyridine is heated with bromotrimethylsilane. Its synthesis from various methods have been reported.
2-Bromo-6-methylpyridine is a building block in the preparation of nitrogen containing heterocyclic compounds.
2-Bromo-6-methylpyridine is an organic compound that belongs to the group of pyridinium halides. It is soluble in common solvents such as water, ethanol, and acetone. 2BMPy has been shown to act as a glutamate receptor antagonist and has been used in the study of glutamate receptors, including their subtypes. This chemical has also been shown to have antioxidant properties and can be used in the prevention of atherosclerosis., Recommanded Product: 2-Bromo-6-methylpyridine