Zhang, Bo; Li, Jun; Pang, Ming; Wang, Ying-Shuo; Liu, Meng-Zhen; Zhao, Hui-Meng published the artcile< Four Discrete Silver Iodobismuthates/Bromobismuthates with Metal Complexes: Syntheses, Structures, Photocurrent Responses, and Theoretical Studies>, COA of Formula: C10H8N2, the main research area is silver iodobismuthate bromobismuthate iron nickel complex preparation crystal structure; photocurrent crystal mol structure silver iodobismuthate bromobismuthate iron nickel.
Using in situ formed metal complexes of [Fe(bipy)3]2+ or [Ni(bipy)3]2+ (bipy = 2,2′-bipyridine) as templates, four new Ag-Bi-X (X = I and Br) compounds are first isolated in the metal-complex-decorated heterometallic halobismuthate family, namely [M(bipy)3]AgBiI6 (M = Fe (1), Ni (2)), [Fe(bipy)3]AgBiBr6 (3), and [Ni(bipy)3]AgBiBr6 (4). Compounds 1-4 feature discrete [AgBiX6]n2n- anions, exhibiting three polymorphisms that may be ascribed to the different stackings and the flexible condensations of [BiX6] octahedrons and [AgX4] tetrahedra/[AgX3] triangles. UV-vis diffuse reflectance analyses reveal that they are narrow band gap semiconductor materials (ca. 1.82-2.13 eV). Intriguingly, the title compounds display excellent photoelec. switching properties, with photocurrent d. following the order 3 > 4 > 2 > 1. In addition, the comparative studies of intermol. interactions, theor. band structures, d. of states, and effective masses of three polymorphisms have also been investigated.
Inorganic Chemistry published new progress about Band structure. 366-18-7 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2, COA of Formula: C10H8N2.