Moi, Rajib; Nath, Karabi; Biradha, Kumar published the artcile< Tailoring Coordination Polymers by Substituent Effect: A Bifunctional CoII-Doped 1D-Coordination Network with Electrochemical Water Oxidation and Nitroaromatics Sensing>, SDS of cas: 3731-53-1, the main research area is cadmium trispyridinylmethylbenzenetricarboxamide isophthalato complex preparation fluorescence catalyst electrochem; crystal structure cadmium trispyridinylmethylbenzenetricarboxamide isophthalato complex; Coordination polymer; fluorescence; nitroaromatic compounds; sensing; water oxidation.
Three CdII coordination polymers (CPs) were synthesized with a tripodal ligand N,N’,N’ ‘-tris(4-pyridinylmethyl)-1,3,5-benzenetricarboxamide in combination with three different substituted isophthalic acids {[Cd2(L)(NIP)2(H2O)2].4H2O}n, (CP-1), {[Cd2(L)(AIP)2(H2O)2].4H2O}n, (CP-2) and {[Cd(L)(BIP) (H2O)].4H2O}n, (CP-3). The substituent groups on the co-ligand had profound effect on the network topologies of the corresponding CPs as well as their properties. Out of the three, CP-1 and CP-2 form 3-dimensional networks whereas CP-3 was a 1-dimensional linear chain with uncoordinated pyridyl sites. Due to its structural features CP-3 was found to show interesting properties. The 1-dimensional CP containing uncoordinated pyridyl site exhibited an excellent ability for doping with CoII which in turn acts as an efficient water oxidation electrocatalyst with required overpotential of 380 mV for an anodic c.d. of 1 mA cm-2. The CP also exhibited luminescence-based detection of nitroaroms. (LOD: 0.003 mM) without any significant interference in presence of other organic compounds
Chemistry – An Asian Journal published new progress about Coordination polymers Role: ARG (Analytical Reagent Use), CAT (Catalyst Use), PEP (Physical, Engineering or Chemical Process), PRP (Properties), SPN (Synthetic Preparation), ANST (Analytical Study), USES (Uses), PROC (Process), PREP (Preparation). 3731-53-1 belongs to class pyridine-derivatives, and the molecular formula is C6H8N2, SDS of cas: 3731-53-1.