Beebeejaun-Boodoo, B. M. P.; Rademeyer, Melanie published the artcile< Coordination polymers and metallocycles of metal halides with n-(aminomethyl)pyridine, n = 3 or 4: Structures and solid-state fluorescence>, Name: Pyridin-4-ylmethanamine, the main research area is cobalt mercury halo aminomethylpyridine coordination polymer metallocycle preparation; crystal structure cobalt mercury halo aminomethylpyridine coordination polymer metallocycle; fluorescence cobalt mercury halo aminomethylpyridine coordination polymer metallocycle.
Coordination polymers and metallocycles formed by the reactions of CoX2 or HgX2, X = Cl-, Br- or I-, with the ditopic organic ligands (L) 3-(aminomethyl)pyridine, 3amp, or 4-(aminomethyl)pyridine, 4amp, are reported. The combination of L = 4amp with CoCl2, CoBr2 or HgI2 yielded one-dimensional coordination polymers of composition [M(L)(X)2]∞, in which the metal ion displays a tetrahedral geometry. Only the combination of L = 3amp with CoCl2 gave a one-dimensional coordination polymer, while the rest of the structures containing this organic ligand were comprised of metallocycles. The metallocyclic rings have a composition [M2(L)2(X)4]n, with n = 1 for L = 3amp and HgBr2, and n = 2 for L = 3amp and CoBr2 or HgI2. Strong N-H. X-M hydrogen bonding interactions are observed in both the coordination polymer and metallocycle structures. The solid-state fluorescence spectra of selected compounds are reported.
Polyhedron published new progress about Coordination polymers Role: RCT (Reactant), RACT (Reactant or Reagent). 3731-53-1 belongs to class pyridine-derivatives, and the molecular formula is C6H8N2, Name: Pyridin-4-ylmethanamine.