Wang, Dong; Jiang, Yuanyang; Dong, Linru; Li, Gaoyu; Sun, Baoying; Desaubry, Laurent; Yu, Peng published the artcile< One-Pot Selective Saturation and Functionalization of Heteroaromatics Leading to Dihydropyridines and Dihydroquinolines>, Related Products of 93-60-7, the main research area is pyridine one pot regioselective dearomatization bond formation; dihydropyridine preparation; quinoline one pot regioselective dearomatization bond formation; dihydroquinoline preparation.
A one-pot regioselective two C-C-bond-forming dearomatization of pyridines and quinolines is disclosed. Two 3,4-betaines are identified for the first time as very useful organic synthons in heterocyclic chem. Furthermore, the chem. reactivity of the prepared trifluoromethyl ketones, a new type of push-pull enones, has been explored to develop straightforward methods for their functionalization. This protocol represents a breakthrough in the dearomatization of heteroaromatics as both the selective saturation and functionalization of heteroaromatics are achieved in high efficiency by the attachment of two substituents, including the valuable trifluoromethyl ketone group.
Journal of Organic Chemistry published new progress about C-C bond formation. 93-60-7 belongs to class pyridine-derivatives, and the molecular formula is C7H7NO2, Related Products of 93-60-7.