Application of 3510-66-5In 2021 ,《Ligand-controlled, Pd/CuH-catalyzed reductive cross-coupling of terminal alkenes and N-heteroaryl bromides》 was published in Chemical Communications (Cambridge, United Kingdom). The article was written by Seo, Sanghyup; Kim, Donghyeon; Kim, Hyunwoo. The article contains the following contents:
The reductive cross-coupling of terminal alkenes and N-heterocyclic bromides had been demonstrated by ligand optimization of Pd and CuH catalysis. The optimized ligands were Briphos, a π-acceptor monodentate phosphorus ligand, for Pd catalysis and DTB-DPPBz, a sterically bulky bidentate phosphorus ligand, for CuH catalysis. These conditions were further applied to the gram-scale production of clathryimine B. In the experiment, the researchers used many compounds, for example, 2-Bromo-5-methylpyridine(cas: 3510-66-5Application of 3510-66-5)
2-Bromo-5-methylpyridine(cas: 3510-66-5) belongs to pyridine. Pyridines, quinolines, and isoquinolines have found a function in almost all aspects of organic chemistry. Pyridine has found use as a solvent, base, ligand, functional group, and molecular scaffold. As structural elements, these moieties are potent electron-deficient groups, metal-directing functionalities, fluorophores, and medicinally important pharmacophores. Application of 3510-66-5