Hagui, Wided; Cordier, Marie; Boixel, Julien; Soule, Jean-Francois published their research in Chemical Communications (Cambridge, United Kingdom) in 2021. The article was titled 《Access to functionalized luminescent Pt(II) complexes by photoredox-catalyzed Minisci alkylation of 6-aryl-2,2′-bipyridines》.HPLC of Formula: 94928-86-6 The article contains the following contents:
Photoredox-mediated C-H bond alkylation of 6-aryl-2,2′-bipyridines with N-(acyloxy)phthalimides RCO2N(CO)2C6H4 catalyzed by [Ir(ppy)3], giving 3-R-6-aryl-2,2′-bipyridines, is reported. The reaction exhibits excellent functional group tolerance, including chiral aliphatic groups. The influence of the incorporated C6′-alkyl group on the photophys. properties of the corresponding (N-N-C) cyclometalated Pt(II) complexes is described, including chiroptical properties. In addition to this study using fac-Tris(2-phenylpyridine)iridium, there are many other studies that have used fac-Tris(2-phenylpyridine)iridium(cas: 94928-86-6HPLC of Formula: 94928-86-6) was used in this study.
fac-Tris(2-phenylpyridine)iridium(cas: 94928-86-6) belongs to pyridine. Pyridine is very deactivated towards electrophilic substitution with respect to benzene. For this reason classical formylation, using methods such as the Gattermann or Vilsmeier reactions, are not generally successful. HPLC of Formula: 94928-86-6