Dedeian, K.; Djurovich, P. I.; Garces, F. O.; Carlson, G.; Watts, R. J. published the artcile< A new synthetic route to the preparation of a series of strong photoreducing agents: fac-tris-ortho-metalated complexes of iridium(III) with substituted 2-phenylpyridines>, Related Products of 370878-69-6, the main research area is photoreducing agent phenylpyridine iridium complex; pyridylbenzene iridium complex.
Reaction of 2-phenylpyridine (Hppy) with Ir(acac)3 (acac = acetylacetonato) in refluxing glycerol gives the fac-tris-ortho-metalate of Ir(III), fac-Ir(ppy)3 in high yield (45%). Phenyl-ring-substituted derivatives of 2-phenylpyridine (R-Hppy) were prepared by cross-coupling of 2-bromopyridine with substituted bromobenzenes. These react with Ir(acac)3 in a manner analogous to Hppy to give similarly high yields (40-75%) of their resp. tris-ortho-metalates, fac-Ir(R-ppy)3.
Inorganic Chemistry published new progress about Electrochemistry. 370878-69-6 belongs to class pyridine-derivatives, and the molecular formula is C33H21F3IrN3, Related Products of 370878-69-6.