Lepeltier, Marc; Dumur, Frederic; Marrot, Jerome; Contal, Emmanuel; Bertin, Denis; Gigmes, Didier; Mayer, Cedric R. published the artcile< Unprecedented combination of regioselective hydrodefluorination and ligand exchange reaction during the syntheses of tris-cyclometalated iridium(III) complexes>, Computed Properties of 370878-69-6, the main research area is fluoropyridine cyclometalated iridium complex preparation unprecedented regioselective hydrodefluorination ligand; crystal mol structure tris fluoropyridine cyclometalated iridium complex.
The first reported combination of regioselective hydro-defluorination and a ligand exchange reaction during the syntheses of neutral iridium(III) complexes is presented. Surprisingly, loss of one fluorine atom per ligand combined with a complete ligand exchange reaction on the transition metal were jointly observed during a bridge-splitting and substitution reaction of two different dimeric iridium(III) precursor complexes with two different ancillary ligands. The regioselectivity of defluorination was evidenced in both cases. The reaction time was identified as a factor strongly impacting the kinetics of the thermally induced reaction.
Dalton Transactions published new progress about Coordinative substitution reaction. 370878-69-6 belongs to class pyridine-derivatives, and the molecular formula is C33H21F3IrN3, Computed Properties of 370878-69-6.