Zhang, Jing; Han, Fu-She published the artcile< Pd-Catalyzed Aerobic Oxidative Heck Cross-Coupling for the Straightforward Construction of Indole δ-Lactams>, Related Products of 93-60-7, the main research area is indolyl amide palladium catalyst oxidative Heck coupling regioselective hetereocyclization; fused indolyl lactam preparation; Catalysis; Chemistry; Organic Chemistry.
A co-ligand-prompted Pd-catalyzed 6-exo-trig intramol. cyclization of indolyl amides via the aerobic oxidative Heck cross-coupling. The method provided a general and efficient way for the construction of [6.5.6]-tricyclic indole δ-lactams. A mechanistic study suggests that a Pd(I)/Pd(III) catalytic cycle should be responsible for effective coupling, which represents a mechanistically alternative pathway when compared with the Pd(0)/Pd(II) cycle proposed for other related coupling reactions.
iScience published new progress about Alkenes Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 93-60-7 belongs to class pyridine-derivatives, and the molecular formula is C7H7NO2, Related Products of 93-60-7.