Shahsavari, Hamid R.; Babadi Aghakhanpour, Reza; Biglari, Abbas; Niazi, Maryam; Mastrorilli, Piero; Todisco, Stefano; Gallo, Vito; Lalinde, Elena; Moreno, M. Teresa; Gimenez, Nora; Halvagar, Mohammad Reza published the artcile< C(sp2)-C(sp2) Reductive Elimination from a Diarylplatinum(II) Complex Induced by a S-S Bond Oxidative Addition at Room Temperature>, Product Details of C10H8N2S2, the main research area is arylplatinum benzothiazolethiolate pyridinethiolate preparation crystal structure; crystal structure diarylplatinum benzothiazolethiolate pyridinethiolate dinuclear platinum lantern complex; mol structure diarylplatinum benzothiazolethiolate pyridinethiolate dinuclear platinum lantern complex; dinuclear platinum lantern complex preparation crystal structure; diarylplatinum complex oxidative addition benzothiazolethiolate pyridinethiolate.
The synthesis and characterization of three six-coordinated Pt(IV) complexes [Pt(Ar)2(S[symbol omitted]N)2] (S[symbol omitted]N = Sbt, benzothiazole-2-thiolate, Ar = p-MeC6H4 (1a), C6F5 (1b); S[symbol omitted]N = Spy, 2-pyridinethiolate, Ar = p-MeC6H4 (1c)) is described. Of these, 1a undergoes, at room temperature and within 18 h, a remarkable C-C reductive elimination process between the aryl ligands to give, as the final products, the stable binuclear lantern complex [Pt2(Sbt)4] (2a) and 4,4′-dimethylbiphenyl. Differently from 1a, solutions of 1b,c are indefinetively stable up to 60° and do not undergo reductive elimination. Complexes 1a-c and 2a were characterized by IR and NMR spectroscopy, high-resolution mass spectrometry, and single-crystal x-ray crystallog. (1b,c and 2a). 1H-19F HOESY experiments on 1b demonstrated the presence of a through-space coupling between proximal F and H atoms of the mol. that are separated by six bonds but are in close spatial proximity.
Organometallics published new progress about Crystal structure. 2127-03-9 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2S2, Product Details of C10H8N2S2.