Huang, Qi; Zard, Samir Z. published the artcile< Modular route to azaindanes>, Electric Literature of 131747-55-2, the main research area is xanthate ester radical cyclization; azaindane preparation.
A convergent radical based route to azaindanes, e.g., I, is described, relying on the degenerative addition transfer of various substituted S-(pyridylmethyl)-O-Et dithiocarbonates (xanthates) to functional alkenes followed by radical cyclization onto the pyridine ring activated by protonation with trifluoroacetic acid. In one case, a richly decorated cyclohepta[b]pyridine could be assembled swiftly by allowing the first adduct to N-phenylmaleimide to undergo addition to N-allylphthalimide prior to cyclization.
Organic Letters published new progress about Heterocyclic compounds Role: SPN (Synthetic Preparation), PREP (Preparation) (azaindanes). 131747-55-2 belongs to class pyridine-derivatives, and the molecular formula is C6H6FNO, Electric Literature of 131747-55-2.