Parada, Giovanny A.; Goldsmith, Zachary K.; Kolmar, Scott; Pettersson Rimgard, Belinda; Mercado, Brandon Q.; Hammarstroem, Leif; Hammes-Schiffer, Sharon; Mayer, James M. published the artcile< Concerted proton-electron transfer reactions in the Marcus inverted region>, Reference of 396092-82-3, the main research area is concerted proton electron transfer reaction Marcus inverted region.
One of the most counterintuitive features of electron transfer kinetics is the inverted region. As Marcus theory predicts and experiments have borne out, electron transfer slows down once the driving force for it becomes especially favorable. Parada et al. now offer evidence for such inverted behavior in proton-coupled electron transfer. Specifically, they examined a series of compounds with phenol bridging anthracene (electron acceptor) and pyridine (proton acceptor) derivatives Time-resolved spectroscopy and accompanying theory revealed slower rates at higher driving forces in the back reaction that follows light-induced intramol. proton and electron transfer.
Science (Washington, DC, United States) published new progress about Charge separation. 396092-82-3 belongs to class pyridine-derivatives, and the molecular formula is C7H9BrN2, Reference of 396092-82-3.