Shen, Ni; Li, Runhan; Liu, Can; Shen, Xuzhong; Guan, Wei; Shang, Rui published the artcile< Photocatalytic Cross-Couplings of Aryl Halides Enabled by o-Phosphinophenolate and o-Phosphinothiophenolate>, Application of C11H16BNO2, the main research area is phosphinophenolate catalyzed cross coupling aryl halide boronate phosphite pyrrole; thiophenolate catalyzed cross coupling aryl halide boronate phosphite pyrrole; arylboronic acid ester preparation; aryl phosphonate preparation; arylpyrrole derivative preparation.
O-Phosphinophenolate and o-phosphinothiophenolate are potent photocatalysts with strong reducing ability to activate aryl chlorides and bromides under visible light for borylation, arylation, and phosphorylation. Exptl. and theor. studies revealed that the o-diphenylphosphino substituent results in a narrow optical gap and facilitates intersystem crossing to access triplet states, which promote phenolate and thiophenolate to function as effective visible-light-photoredox catalysts. The results presented herein suggest promising utility of synthetically modified phenolates and thiophenolates as photoredox catalysts.
ACS Catalysis published new progress about Amination. 329214-79-1 belongs to class pyridine-derivatives, and the molecular formula is C11H16BNO2, Application of C11H16BNO2.