Name: Pyridin-3-ylboronic acidIn 2019 ,《A Mild and Direct Site-Selective sp2 C-H Silylation of (Poly)Azines》 was published in Journal of the American Chemical Society. The article was written by Gu, Yiting; Shen, Yangyang; Zarate, Cayetana; Martin, Ruben. The article contains the following contents:
A base-mediated protocol that allows for the site-selective sp2 C-H silylation of pyridines, pyrazines, pyridazines, pyrimidines and quinolines by Et3SiBpin is described. The substitution typically proceeds in 4- or 2-position of the pyridine ring. This method is distinguished by its mild conditions, simplicity and excellent site-selective modulation for a diverse set of azines, even in the context of late-stage functionalization, while exhibiting orthogonal reactivity with classical silylation reactions.Pyridin-3-ylboronic acid(cas: 1692-25-7Name: Pyridin-3-ylboronic acid) was used in this study.
Pyridin-3-ylboronic acid(cas: 1692-25-7) belongs to pyridine. Pyridines, quinolines, and isoquinolines have found a function in almost all aspects of organic chemistry. Pyridine has found use as a solvent, base, ligand, functional group, and molecular scaffold. As structural elements, these moieties are potent electron-deficient groups, metal-directing functionalities, fluorophores, and medicinally important pharmacophores. Name: Pyridin-3-ylboronic acid