Ando, Shin; Hirota, Yurina; Matsunaga, Hirofumi; Ishizuka, Tadao published the artcile< Nickel-catalyzed N-arylation of amines with arylboronic acids under open air>, COA of Formula: C11H10N2, the main research area is arylamine preparation; amine arylboronic acid Chan Lam coupling nickel catalyst.
Novel NHC-Ni complex was developed and used for the synthesis of arylamines via Chan-Lam coupling of amines with arylboronic acids. This novel NHC-Ni complex in combination with 4,4′-dimethyl-2,2′-bipyridine, however, proved to be an effective catalyst that lowered the required catalyst loading to only 2.0 mol%. The robustness of NHC complexes toward oxidative conditions and high level of σ-donating ability of NHC ligands could be reason for catalysis.
Tetrahedron Letters published new progress about Arylation. 22961-45-1 belongs to class pyridine-derivatives, and the molecular formula is C11H10N2, COA of Formula: C11H10N2.