Qin, Yin; Li, Yilin; Guo, Kaimeng; Tang, Huabiao; Hou, Lifen; Li, Gang published the artcile< Water-assisted proton conductivity of two highly stable imidazole multi-carboxylate-based MOFs>, Safety of 2,2′-Bipyridine, the main research area is crystal structure manganese zinc carboxylimidazoledicarboxylate bipyridine metal organic framework; manganese zinc carboxylimidazoledicarboxylate bipyridine MOF preparation proton conductivity.
Two new chain-like metal-organic frameworks (MOFs), {[Mn(o-CPhH2IDC)(4.4′-bipy)0.5(H2O)2]·3H2O}n (1) (o-CPhH4IDC = 2-phenyl(2-carboxyl)-1-H-imidazole-4,5-dicarboxylic acid; 4,4′-bipy = 4,4′-bipyridine) and {[Zn5(o-CPhH2IDC)2(o-CPhHIDC)2(2,2′-bipy)5]·5H2O}n (2) (2,2′-bipy = 2,2′-bipyridine) were designed and solvothermally or hydrothermally synthesized and structurally characterized. By SEM determinations and PXRD analyses, the high H2O stability and acid and alkali resistance of both MOFs were determined The affluent H-bond networks inside the frameworks formed by imidazole multi-carboxylate ligands and H2O mols. would favor the transfer of protons. Also, the temperature- and humidity-dependent proton conduction properties of the two MOFs were demonstrated. Also, the proton conducting mechanisms will be highlighted herein.
New Journal of Chemistry published new progress about Activation energy (proton conductivity). 366-18-7 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2, Safety of 2,2′-Bipyridine.