Mathuri, Ashis; Pramanik, Milan; Parida, Amarchand; Mal, Prasenjit published the artcile< Disulfide metathesis via sulfur···iodine interaction and photoswitchability>, Synthetic Route of 2127-03-9, the main research area is unsym disulfide preparation; sym disulfide cross metathesis reaction photoswitchable.
Herein, the synthesis of unsym. diaryl disulfides RSSR1 (R = 2-MeC6H4, furan-2-ylmethyl, pyridin-2-yl, etc., R1 = CH2CHMe2, cyclohexyl, 4-ClC6H4, etc.) from two sym. disulfides RSSR and R1SSR1 via a cross-metathesis reaction which was controlled by a weak sulfur···iodine (S···I) interaction is reported. The unsym. disulfides were stable in acetonitrile solution in the presence of N-iodosuccinimide (NIS), and were found to be reversibly photoswitchable to the sym. disulfides under visible light irradiation
Organic & Biomolecular Chemistry published new progress about Aromatic compounds, disulfides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 2127-03-9 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2S2, Synthetic Route of 2127-03-9.