Nishiyama, Hisao published the artcile< Synthesis and reactivity of organometallic complexes with C2-symmetrical optically active nitrogen-ligands. Asymmetric catalytic oxidation>, Name: 6,6′-Bis(4-(S)-isopropyl-2-oxazolinyl)-2,2′-bipyridine, the main research area is ruthenium oxazolinyl pyridine catalyst asym oxidation; oxazolinyl bipyridine ruthenium catalyst asym oxidation.
Two types of optically active nitrogen-ligands having C2-symmetry, bis(oxazolinyl)pyridine (Pybox) and bis(oxazolinyl)bipyridine (Bipymox), were developed for asym. catalytic reactions. The nitrogen ligands gave stable complexes by the reaction with ruthenium(II) chloride complex. The structures of the Pybox- and Bipymox-ruthenium complexes were analyzed by x-ray and electrochem. Their complexes of ruthenium(II) exhibited strong activities of oxidation of secondary alcs. and epoxidation of olefins with asym. induction. During this study, highly efficient enantioselective hydrosilylation of ketones and cyclopropanation reaction were discovered.
Asahi Garasu Zaidan Josei Kenkyu Seika Hokoku published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 147409-41-4 belongs to class pyridine-derivatives, and the molecular formula is C22H26N4O2, Name: 6,6′-Bis(4-(S)-isopropyl-2-oxazolinyl)-2,2′-bipyridine.