Uraguchi, Daisuke; Kinoshita, Natsuko; Kizu, Tomohito; Ooi, Takashi published the artcile< Synergistic Catalysis of Ionic Bronsted Acid and Photosensitizer for a Redox Neutral Asymmetric α-Coupling of N-Arylaminomethanes with Aldimines>, COA of Formula: C33H21F3IrN3, the main research area is aldimine arylaminomethane chiral arylaminophosphonium iridium enantioselective coupling visible light; aryl diamine stereoselective preparation; chiral arylaminophosphonium photosensitizer iridium enantioselective coupling synergistic catalyst.
A redox neutral, highly enantioselective coupling between N-arylaminomethanes and N-sulfonyl aldimines was developed by harnessing the efficient catalysis of P-spiro chiral arylaminophosphonium barfate and a transition-metal photosensitizer under visible light irradiation This mode of synergistic catalysis provides a powerful strategy for controlling the bond-forming processes of reactive radical intermediates.
Journal of the American Chemical Society published new progress about Aldimines Role: RCT (Reactant), RACT (Reactant or Reagent). 370878-69-6 belongs to class pyridine-derivatives, and the molecular formula is C33H21F3IrN3, COA of Formula: C33H21F3IrN3.