Jin, Songyang; Geng, Xinxin; Li, Yujun; Zheng, Ke published the artcile< Phosphoric Acid Mediated Light-Induced Minisci C-H Alkylation of N-Heteroarenes>, Recommanded Product: 3-(Methoxycarbonyl)pyridine, the main research area is green phosphate catalyst Minisci alkylation heteroarene redox active ester.
Herein, we report an environmentally-friendly light-induced Minisci alkylation of N-heteroarenes with a broad substrate scope using di-Ph phosphate as catalyst under metal- and photocatalyst-free conditions. The radical precursor redox-active esters (RAEs) were introduced as alkylating reagents for the functionalization of N-heteroarene derivatives including pyridine, quinoline, and isoquinoline. Mechanistic studies suggested that di-Ph phosphate played a key role via hydrogen bonding in the catalytic cycle.
European Journal of Organic Chemistry published new progress about Alkylation (Minisci). 93-60-7 belongs to class pyridine-derivatives, and the molecular formula is C7H7NO2, Recommanded Product: 3-(Methoxycarbonyl)pyridine.