Chambers, R.J.’s team published research in Synthetic Communications in 1997 | CAS: 29682-15-3

Methyl 5-bromopicolinate(cas: 29682-15-3) belongs to pyridine. The basicity and metallophilic high donor number of these π-deficient systems has long favored them as ligands in metal catalysis. The last decade saw pyridine assume a stronger role as functional group for directed C–H oxidation/activation.Related Products of 29682-15-3

Related Products of 29682-15-3In 1997 ,《Regiospecific carboalkoxylation of 2,5-dibromopyridine》 appeared in Synthetic Communications. The author of the article were Chambers, R.J.; Marfat, A.. The article conveys some information:

Carboalkoxylation of 2,5-dibromopyridine with carbon monoxide and an alc. in the presence of palladium acetate and 1,1′-bis(diphenylphosphino)ferrocene (dppf) occurs regiospecifically to afford esters of 5-bromopyridine-2-carboxylic acid in good yield. In the part of experimental materials, we found many familiar compounds, such as Methyl 5-bromopicolinate(cas: 29682-15-3Related Products of 29682-15-3)

Methyl 5-bromopicolinate(cas: 29682-15-3) belongs to pyridine. The basicity and metallophilic high donor number of these π-deficient systems has long favored them as ligands in metal catalysis. The last decade saw pyridine assume a stronger role as functional group for directed C–H oxidation/activation.Related Products of 29682-15-3

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem