Martell, Mark; Ocheje, Michael U.; Gelfand, Benjamin S.; Rondeau-Gagne, Simon; Welch, Gregory C. published their research in New Journal of Chemistry in 2021. The article was titled 《Sidechain engineering of N-annulated perylene diimide molecules》.Recommanded Product: 2-(Bromomethyl)pyridine hydrobromide The article contains the following contents:
The synthesis and characterization of six new N-annulated perylene diimide (N-PDI) mols. consisting of different alkyl-based heteroatom and waxy infused sidechains is reported. Amino, urea, quaternary Me ammonium, iminopyridine, hexadecyl and pyridine moieties were all appended to the pyrrolic N-position of N-annulated PDI. These N-PDI derivatives have been synthesized using facile SN2 chem. resulting in high yields and without the need for purification via column chromatog. To further demonstrate the functional diversification offered by N-PDI we appended a cyano group to the 6,7-bay positions opposite the N-annulation site and tested utility in organic field effect transistor devices. Complete characterization of these N-PDI derivatives was completed using UV-Vis spectroscopy, cyclic voltammetry and solubility determination to observe how the appended sidechains affect structure-properties relationships. The experimental part of the paper was very detailed, including the reaction process of 2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8Recommanded Product: 2-(Bromomethyl)pyridine hydrobromide)
2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.Recommanded Product: 2-(Bromomethyl)pyridine hydrobromide