On May 27, 2005, Toele, P.; Glasbeek, M. published an article.Electric Literature of 75449-26-2 The title of the article was Ultrafast excited-state intramolecular double proton transfer dynamics of [2,2′-bipyridyl]-3,3′-diamine. And the article contained the following:
A femtosecond fluorescence upconversion study of [2,2′-bipyridyl]-3,3′-diamine (BP(NH2)2), in liquid solution, is reported. It is concluded that photoexcited BP(NH2)2 undergoes a branched intramol. double proton transfer reaction comprising two trajectories: (a) ultrafast double proton transfer (<100 fs) followed by twisting (∼250 fs); (b) a combined process of double proton transfer and twisting, with an overall reaction time of ∼250 fs. Picosecond transient fluorescence is attributed to vibrational cooling in the excited product state. The lifetime of ∼10 ps of the tautomer product state is indicative of conical intersection of the product- and ground-state potential energy surfaces. The experimental process involved the reaction of [2,2'-Bipyridine]-3,3'-diamine(cas: 75449-26-2).Electric Literature of 75449-26-2
The Article related to fluorescence upconversion study bipyridyldiamine photoinduced intramol double proton transfer, excited state intramol double proton transfer dynamics bipyridyldiamine, photoinduced tautomerization photophys photochem bipyridyldiamine and other aspects.Electric Literature of 75449-26-2