On October 15, 2021, Wang, Qiang; Wang, Yujia; Chen, Lin; Sun, Xuzhuo; Li, Bo; He, Shuanglin; Li, Jun; Wang, Ning published an article.Formula: C5H5NO3S The title of the article was Introducing electrostatic interaction into Ru(bda) complexes for promoting water-oxidation catalysis. And the article contained the following:
Ru(bda) (H2bda = 2,2′-bipyridine-6,6′-dicarboxylic acid) complex is a kind of well-known water oxidation catalyst, which goes through the bimol. I2M mechanism with an inter-catalyst O-O coupling step. Recently, we developed two facile strategies to accelerate O-O coupling via introducing the electrostatic interaction into Ru(bda)-catalyzed systems. In this work, a series of Ru(bda) complexes with different charged groups on different positions were synthesized to demonstrate the general applicability of these design strategies. It found these catalytic systems with attractive electrostatic interaction display much better activity, and the position of the charged substituents also has a significant influence on the catalytic activity. The experimental process involved the reaction of Pyridine-3-sulfonic acid(cas: 636-73-7).Formula: C5H5NO3S
The Article related to ruthenium bipyridine complex electrostatic interaction water oxidation, Placeholder for records without volume info and other aspects.Formula: C5H5NO3S