Li, Yanru; Miyamoto, Shoto; Torigoe, Takeru; Kuninobu, Yoichiro published an article in 2021, the title of the article was Regioselective C(sp3)-H alkylation of a fructopyranose derivative by 1,6-HAT.Formula: C36H22F16IrN4P And the article contains the following content:
Regioselective C(sp3)-H alkylation of a fructopyranose derivative using electron-deficient alkenes as alkylation reagents was achieved. The reaction proceeded via 1,6-hydrogen atom transfer under photoredox iridium catalysis. Several functional groups were introduced into the fructopyranose derivative The experimental process involved the reaction of 4,4′-Bis(trifluoromethyl)-2,2′-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl] iridium(III) hexafluorophosphate(cas: 2229858-27-7).Formula: C36H22F16IrN4P
The Article related to regioselective alkylation catalyst alkene fructopyranose glycoside preparation, photoredox iridium catalysis hydrogen transfer alkylation, Carbohydrates: Glycosides and other aspects.Formula: C36H22F16IrN4P