《Organic-Inorganic Hybrid Cerium-Encapsulated Selenotungstate Including Three Building Blocks and Its Electrochemical Detection of Dopamine and Paracetamol》 was published in Inorganic Chemistry in 2020. These research results belong to Jiang, Jun; Liu, Lulu; Liu, Guoping; Wang, Dan; Zhang, Yan; Chen, Lijuan; Zhao, Junwei. Product Details of 1692-25-7 The article mentions the following:
A novel organic-inorganic hybrid cerium-encapsulated selenotungstate comprising three polyoxotungstate building units Na16H6{[Ce3W4O10(H2O)9(CH3COO)3]2(Se2W7O30)(B-α-SeW9O33)4}·(C5H8NBO3)·119H2O (1) was synthesized by the portfolio approach of an in situ self-assembly reaction and step-by-step synthesis. The hybrid polyoxoanion of 1 is constructed from an acetate-coordinated heterometallic {[(Ce3W4O10)(H2O)9(CH3COO)3]2(Se2W7O30)}10+ core encompassing four trilacunary [B-α-SeW9O33]8- subunits. Interestingly, the heterometallic core contains a remarkable [Se2W7O30]10- building block in which seven WVI atoms form a W7 plane and two SeIV atoms are situated on two opposite faces of the W7 plane. In addition, the electrochem. performances of the 1@CFMCN composite (CFMCN: carboxyl-functionalized multiwalled carbon nanotube) were investigated. The 1@CFMCN/GCE (GCE: glass carbon electrode) sensor demonstrates a promising potential in electrochem. sensing dopamine (DPA) or paracetamol (PCM) or even simultaneously detecting DPA and PCM with low limits of 0.053μM for DPA and 2.03μM for PCM over a wide linear range at high sensitivity. A novel organic-inorganic hybrid selenotungstate was synthesized via the portfolio approach of an in situ self-assembly reaction and step-by-step synthesis. Its electrochem. sensing properties toward DPA and PCM were investigated. In addition to this study using Pyridin-3-ylboronic acid, there are many other studies that have used Pyridin-3-ylboronic acid(cas: 1692-25-7Product Details of 1692-25-7) was used in this study.
Pyridin-3-ylboronic acid(cas: 1692-25-7) belongs to pyridine. Pyridine is very deactivated towards electrophilic substitution with respect to benzene. For this reason classical formylation, using methods such as the Gattermann or Vilsmeier reactions, are not generally successful. Product Details of 1692-25-7