ãVisible-Light-Mediated C-H Alkylation of Pyridine Derivativesã?was written by Rammal, Fatima; Gao, Di; Boujnah, Sondes; Gaumont, Annie-Claude; Hussein, Aqeel A.; Lakhdar, Sami. Quality Control of 4-CyanopyridineThis research focused onvisible light alkylation pyridine derivative alkane. The article conveys some information:
We report herein a visible-light-mediated C-H alkylation of pyridine derivatives that proceeds by simple combination of a large variety of N-alkoxypyridinium ions with alkanes in the presence of 2 mol % of fac-Ir(ppy)3 under blue illumination. The mild reaction conditions together with the high group functional tolerance make of this process a useful synthetic platform for the construction of structurally strained heterocycles. Detailed mechanistic investigations, including d. functional theory calculations and quantum yield measurement, allowed us to understand factors controlling the reactivity and the selectivity of the reaction. The results came from multiple reactions, including the reaction of 4-Cyanopyridine(cas: 100-48-1Quality Control of 4-Cyanopyridine)
4-Cyanopyridine(cas: 100-48-1) belongs to pyridine. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Additionally, pyridine-based natural products continue to be discovered and studied for their properties and to understand their biosynthesis.Quality Control of 4-Cyanopyridine