Bare Magnetite-Promoted Oxidative Hydroxylation of Arylboronic Acids and Subsequent Conversion into Phenolic Compounds was written by Cho, Hyun-A.;Lee, Yong-Ki;Kim, Seung-Hoi. And the article was included in Synlett in 2022.Recommanded Product: 700-16-3 The following contents are mentioned in the article:
The simple combination of readily available, recoverable, and recyclable magnetite (Fe3O4) nanoparticles and an environmentally friendly oxidant (H2O2) induced oxidative hydroxylation of arylboronic acids into their corresponding phenols ArOH [Ar = Ph, 2-MeC6H4, 4-MeC6H4, etc.] under mild conditions. Moreover, subsequent arylation or alkylation of intermediate with appropriate electrophiles was accomplished in a one-pot system, leading to the formation of halophenols and phenolic derivs ArOR [Ar = Ph, 3-MeC6H4, 4-MeC6H4, etc.; R = Bn, CH2(4-FC6H4), allyl, etc]. This study involved multiple reactions and reactants, such as 2,3,4,5,6-Perfluoropyridine (cas: 700-16-3Recommanded Product: 700-16-3).
2,3,4,5,6-Perfluoropyridine (cas: 700-16-3) belongs to pyridine derivatives. In contrast to benzene, Pyridine’s electron density is not evenly distributed over the ring, reflecting the negative inductive effect of the nitrogen atom. Pyridine derivatives are also useful as small-molecule 伪-helix mimetics that inhibit protein-protein interactions, as well as functionally selective GABA ligands.Recommanded Product: 700-16-3