Diverse reactivity of carbenes and silylenes towards fluoropyridines was written by Kundu, Gargi;Ajithkumar, V. S.;Bisai, Milan Kumar;Tothadi, Srinu;Das, Tamal;Vanka, Kumar;Sen, Sakya S.. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2021.Application of 700-16-3 The following contents are mentioned in the article:
The reaction of IDipp with C5F5N led to functionalization of all three carbon atoms of the imidazole ring with HF2– as the counter-anion (1). Reactivity with 2,3,5,6-tetrafluoropyridine gives only C-F bond activation leaving C-H bonds intact (5b). The reaction of SIDipp with C5F5N in the presence of BF3 afforded the ring cleavage product (3). Analogous reactions with silylene led to oxidative addition at the Si(
2,3,4,5,6-Perfluoropyridine (cas: 700-16-3) belongs to pyridine derivatives. The pyridine ring occurs in many important compounds, including agrochemicals, pharmaceuticals, and vitamins. Reduced pyridines, namely tetrahydropyridines, dihydropyridines and piperidines, are found in numerous natural and synthetic compounds. The synthesis and reactivity of these compounds have often been driven by the fact many of these compounds have interesting and unique pharmacological properties. Application of 700-16-3