Isotypic Transformation Principle in Molecular Crystals. Analysis of Supramolecular Architecture of Fluorinated Benzenes and Pyridines was written by Shishkin, Oleg V.;Merz, Klaus;Vasylyeva, Vera;Zubatyuk, Roman I.. And the article was included in Crystal Growth & Design in 2018.Application In Synthesis of 2,3,4,5,6-Perfluoropyridine The following contents are mentioned in the article:
A systematic topol. anal. of fluorinated pyridines and benzenes is reported. F and N atoms are considered to be isolobal with respect to the supramol. architecture in the crystalline phase. The comparison of the intermol. interaction energies demonstrates that N atom within the aromatic ring and F as a substituent both induce the same type of mol. arrangement in the solid state. Based on this, a general isotypic transformation principle for mol. crystals is suggested. This study involved multiple reactions and reactants, such as 2,3,4,5,6-Perfluoropyridine (cas: 700-16-3Application In Synthesis of 2,3,4,5,6-Perfluoropyridine).
2,3,4,5,6-Perfluoropyridine (cas: 700-16-3) belongs to pyridine derivatives. The ring atoms in the pyridine molecule are sp2-hybridized. The nitrogen is involved in the è?bonding aromatic system using its unhybridized p orbital. The lone pair is in an sp2 orbital, projecting outward from the ring in the same plane as the è?bonds. Pyridine groups exist in countless molecules, and their applications include catalysis, drug design, molecular recognition, and natural product synthesis.Application In Synthesis of 2,3,4,5,6-Perfluoropyridine