Kuroboshi, Manabu published the artcileElectroreductive generation of recyclable organic reductant from N,N’-dioctyl-4,4′-bipyridinium and Pd-catalyzed reductive coupling of aryl halides, Computed Properties of 36437-30-6, the main research area is electroreductive generation recyclable organic reductant dioctylbipyridinium electroreduction; palladium catalyzed reductive coupling aryl halide electroreductive generation reductant.
Electroreduction of N,N’-dioctyl-4,4′-bipyridinium bis(triflimide) [C8V2+][Tf2N-]2 in THF gave a dark blue solution of the corresponding quinoid C8V0, which worked as an efficient organic reductant for Pd-catalyzed reductive coupling of aryl bromides to give the corresponding biphenyl derivatives in good yields. After usual workup, [C8V2+][Tf2N-]2 was recovered and reused for generation of the organic reductant C8V0.
Synlett published new progress about Aryl halides Role: RCT (Reactant), RACT (Reactant or Reagent). 36437-30-6 belongs to class pyridine-derivatives, name is 1,1-Di-n-octyl-4,4-bipyridinium Dibromide, and the molecular formula is C26H42Br2N2, Computed Properties of 36437-30-6.