Dau, Phuong V. published the artcileSingle-Atom Ligand Changes Affect Breathing in an Extended Metal-Organic Framework, Product Details of C13H13N, the publication is Inorganic Chemistry (2012), 51(10), 5671-5676, database is CAplus and MEDLINE.
2-Phenylpyridine-5,4′-dicarboxylic acid (1, dcppy), a derivative of 4,4′-biphenyldicarboxylic (2, bpdc) was used as the organic linking component for several metal-organic frameworks (MOFs). The pyridine component of 1 does not interfere with the solvothermal synthetic procedure, and hence both 1 and 2 form similar isoreticular MOFs. Zr4+-based UiO-67-dcppy, Al3+-based DUT-5-dcppy, Zn2+-based DMOF-1-dcppy, and interpenetrated Zn2+-based BMOF-1-dcppy were readily synthesized from 1. Similarly, isostructural frameworks from 2 were prepared (UiO-67, DUT-5, DMOF-1-bpdc, and interpenetrated BMOF-1-bpdc). The structures and phys. properties of these frameworks were characterized by powder x-ray diffraction (PXRD), single XRD, TGA, and gas sorption anal. Generally, frameworks prepared from 1 or 2 displayed similar properties; however, gas sorption data showed that BMOF-1-dcppy displayed a very large hysteresis with N2 and CO2 suggestive of possible framework flexibility. In contrast, the analogous framework prepared from 2 (BMOF-1-bpdc) showed low uptake of N2 and CO2. The substantial difference in the gas sorption behavior of these MOFs is attributed to the pyridine nature of 1 that results in weakened π-π interactions between the interpenetrated nets.
Inorganic Chemistry published new progress about 85237-71-4. 85237-71-4 belongs to pyridine-derivatives, auxiliary class Pyridine,Benzene, name is 5-Methyl-2-(p-tolyl)pyridine, and the molecular formula is C13H13N, Product Details of C13H13N.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem