Maidan, Ruben published the artcileApplication of multielectron charge relays in chemical and photochemical debromination processes. The role of induced disproportionation of N,N’-dioctyl-4,4′-bipyridinium radical cation in two-phase systems, Application of 1,1-Di-n-octyl-4,4-bipyridinium Dibromide, the main research area is disproportionation bipyridinium cation radical debromination; photochem reduction bipyridinium disproportionation.
Photochem. and chem. reduction of N,N’-dioctyl-4,4′-bipyridinium to the corresponding radical cation (I) leads to induced disproportionation of I in an aqueous-organic, 2-phase system, yielding the 2-electron reduction product II. The induced disproportionation is a result of opposite solubility properties of the disproportionation products in the 2 phases. II mediates the debromination of 1,2- and 1,1-dibromo substrates.
Journal of the American Chemical Society published new progress about Debromination. 36437-30-6 belongs to class pyridine-derivatives, name is 1,1-Di-n-octyl-4,4-bipyridinium Dibromide, and the molecular formula is C26H42Br2N2, Application of 1,1-Di-n-octyl-4,4-bipyridinium Dibromide.