Culp, Jeffrey T. published the artcileScreening Hofmann Compounds as CO2 Sorbents: Nontraditional Synthetic Route to Over 40 Different Pore-Functionalized and Flexible Pillared Cyanonickelates, SDS of cas: 1008506-24-8, the publication is Inorganic Chemistry (2013), 52(8), 4205-4216, database is CAplus and MEDLINE.
A simple reaction scheme based on the heterogeneous intercalation of pillaring ligands (HIPLs) provides a convenient method for systematically tuning pore size, pore functionality, and network flexibility in an extended series of pillared cyanonickelates (PICNICs), commonly named Hofmann compounds The versatility of the approach is demonstrated through the preparation of over 40 different PICNICs containing pillar ligands ranging from â? to â?5 Ã in length and modified with a wide range of functional groups, including fluoro, aldehyde, alkylamine, alkyl, aryl, trifluoromethyl, ester, nitro, ether, and non-metalated 4,4′-bipyrimidine. The HIPL method involves reaction of a suspension of preformed polymeric sheets of powd. anhydrous Ni cyanide with an appropriate pillar ligand in refluxing organic solvent, converting the planar [Ni2(CN)4]n networks into polycrystalline three-dimensional porous frameworks containing the organic pillar ligand. Preliminary studies indicate that the HIPL reaction is also amenable to forming Co(L)Ni(CN)4, Fe(L)Ni(CN)4, and Fe(L)Pd(CN)4 networks. The materials show variable adsorption behavior for CO2 depending on the pillar length and pillar functionalization. Several compounds show structurally flexible behavior during the adsorption and desorption of CO2. The newly discovered flexible compounds include two flexible Fe(L)Ni(CN)4 derivatives that are structurally related to previously reported porous spin-crossover compounds The preparations of 20 pillar ligands based on ring-functionalized 4,4′-dipyridyls, 1,4-bis(4-pyridyl)benzenes, and N-(4-pyridyl)isonicotinamides are also described.
Inorganic Chemistry published new progress about 1008506-24-8. 1008506-24-8 belongs to pyridine-derivatives, auxiliary class Pyridine,Boronic acid and ester,Ether,Pyridine,Boronic Acids,Boronic acid and ester, name is 3-Methoxypyridine-4-boronic acid, and the molecular formula is C6H8BNO3, SDS of cas: 1008506-24-8.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem