Yang, Lei published the artcilePalladium(0)-catalyzed asymmetric C(sp3)-H arylation using a chiral binol-derived phosphate and an achiral ligand, Recommanded Product: 2-Bromopyridin-3-amine, the publication is Chemical Science (2017), 8(2), 1344-1349, database is CAplus and MEDLINE.
The first efficient palladium(0)-catalyzed enantioselective C(sp3)-H activation reaction using a catalytic chiral base and an achiral phosphine ligand was reported. Fine-tuning the binol-derived phosphoric acid pre-catalyst and the reaction conditions was found to be crucial to achieve high levels of enantioselectivity for a variety of indoline products containing both tri- and tetrasubstituted stereocenters.
Chemical Science published new progress about 39856-58-1. 39856-58-1 belongs to pyridine-derivatives, auxiliary class Pyridine,Bromide,Amine, name is 2-Bromopyridin-3-amine, and the molecular formula is C16H20N2, Recommanded Product: 2-Bromopyridin-3-amine.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem