van der Vlugt, Jarl Ivar’s team published research in Inorganic Chemistry in 48 | CAS: 338800-13-8

Inorganic Chemistry published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C10H11NO4, Recommanded Product: 2,6-Bis((di-tert-butylphosphino)methyl)pyridine.

van der Vlugt, Jarl Ivar published the artcileCuI Complexes with a Non-innocent PNP Ligand: Selective Dearomatization and Electrophilic Addition Reactivity, Recommanded Product: 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, the publication is Inorganic Chemistry (2009), 48(16), 7513-7515, database is CAplus and MEDLINE.

The neutral, T-shaped complex CuI(PN–PtBu) (2)featuring a de-aromatized 2,6-bis[(di-tert-butylphosphino)methyl]pyridine (PN–PtBu) PNP-pincer ligand, is shown to interact rapidly with electrophiles. Furthermore, C-C bond formation onto the deprotonated methylene-bridgehead carbon is observed with MeOTf as the electrophile. The mol. structure of the methylated derivatives were determined by X-ray crystallog. This represents the first case of selective modification of the lutidine-based backbone of such non-innocent PNP ligands. Theor. calculations support the formation of monomeric complex 2 and indicate the high reactivity of the methylene fragment in this CuI complex.

Inorganic Chemistry published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C10H11NO4, Recommanded Product: 2,6-Bis((di-tert-butylphosphino)methyl)pyridine.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem