Jayakumar, K. published the artcileSpectral, thermal and DFT studies of novel nickel(II) complexes of 2-benzoylpyridine-N4-methyl-3- thiosemicarbazone: Crystal structure of a square planar azido-nickel(II) complex, COA of Formula: C12H9NO, the publication is Journal of Molecular Structure (2022), 132257, database is CAplus.
Novel six Ni(II) complexes of an NNS donor 2-benzoylpyridine-N4-methyl-3- thiosemicarbazone(HL) were synthesized and characterized. Various physicochem. techniques are applied for the study of the coordination behavior of the thiosemicarbazone to the nickel center. In all the complexes, thiosemicarbazone is coordinated in the thiolate form. A four coordinated Ni(II) complex [NiLN3] is crystallized and its mol. and crystal structures are determined by single-crystal x-ray crystallog. Single-crystal XRD reveals that the complex got crystallized in the monoclinic space group P21/n and nickel(II) has a square planar environment. Intramol. hydrogen bonding interactions make the complex more rigid and in the crystal lattice, the intermol. hydrogen bonding interactions generate a supramol. 1 D chain. The chem. reactivity behavior of the HL and six Ni(II) complexes was evaluated with the CAM-B3LYP quantum chem. calculations The validity of electronic structure principles like Maximum Hardness, Min. Polarizability, and Min. Electrophilicity Principle in the study is discussed.
Journal of Molecular Structure published new progress about 91-02-1. 91-02-1 belongs to pyridine-derivatives, auxiliary class Pyridine,Benzene,Ketone, name is Phenyl(pyridin-2-yl)methanone, and the molecular formula is C12H9NO, COA of Formula: C12H9NO.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem