Umemoto, Teruo’s team published research in Bulletin of the Chemical Society of Japan in 59 | CAS: 107263-95-6

Bulletin of the Chemical Society of Japan published new progress about 107263-95-6. 107263-95-6 belongs to pyridine-derivatives, auxiliary class Fluorination reagent, name is 1-Fluoropyridiniumtriflate, and the molecular formula is C8H15ClN2, HPLC of Formula: 107263-95-6.

Umemoto, Teruo published the artcileα-Fluorination of sulfides with N-fluoropyridinium triflates, HPLC of Formula: 107263-95-6, the publication is Bulletin of the Chemical Society of Japan (1986), 59(11), 3625-9, database is CAplus.

The reaction of RSCH2R1 [I R = Ph, PhCH2, C6H4Cl-4, Me, dodecyl; R1 = H, CO2Et, CO2Me, CH2CH(CO2Me)NHCOCF3] with N-fluoropyridium salts II (X = CF3SO3, BF4), III, and IV was examined While the fluorinating power increased in the order of II (X = CF3SO3) < III < IV, the yield of α-fluoro sulfide decreased in the order of II > III, and IV no longer produced the α-fluoro sulfide. II (X = CF3SO3) was more reactive than II (X = BF4). Thus, RSCHFR1 were prepared by α-fluorination of I with II (X = CF3SO3) under mild conditions. RS(O)nCHFR1 (n = 1, 2) were easily prepared by α-fluorination of I with II, followed by oxidation

Bulletin of the Chemical Society of Japan published new progress about 107263-95-6. 107263-95-6 belongs to pyridine-derivatives, auxiliary class Fluorination reagent, name is 1-Fluoropyridiniumtriflate, and the molecular formula is C8H15ClN2, HPLC of Formula: 107263-95-6.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem