Binding affinity of pyridines with AmIII/CmIII elucidated by density functional theory calculations was written by Yu, Jie;Ma, Jun;Yang, Chuting;Yu, Haizhu. And the article was included in Dalton Transactions in 2019.Related Products of 644-98-4 This article mentions the following:
In recent decades, N-heterocyclic ligands have been extensively used in the separation of lanthanides/actinides, whereas the selective extraction of amercium or curium has been very challenging. Using d. functional theory calculations, this study is devoted to the investigation of the binding affinity of a series of modeling pyridine ligands with AmIII and CmIII. The structure-property correlations between the amercium and curium systems and the binding affinity were obtained, and promising strategies for efficient separation of AmIII/CmIII were proposed. In the experiment, the researchers used many compounds, for example, 2-Isopropylpyridine (cas: 644-98-4Related Products of 644-98-4).
2-Isopropylpyridine (cas: 644-98-4) belongs to pyridine derivatives. Pyridine has a dipole moment and a weaker resonant stabilization than benzene (resonance energy 117 kJ·mol−1 in pyridine vs. 150 kJ·mol−1 in benzene). Pyridine groups exist in countless molecules, and their applications include catalysis, drug design, molecular recognition, and natural product synthesis.Related Products of 644-98-4